The black rim is merely the shadow/refraction cast by the rim onto the opalescence (which stops just below the inside rim - visible in pic 3).
Under normal light it's still quite browny-red, as well as opalescent. But of the two, unless in very bright, direct, and shadowless daylight, the brown is the dominant colour. That said, it's hard to place the two as distinct layers. When viewed from the inside of the vase, it appears as though the opalescence is on the front and the brown is behind it, but this is also true when viewed from the other side, outside of the vase (if that makes sense?).
It's a hard one to photograph, because there's seemingly so much going on.