I see this sort of glass roof tile for sale on eBay UK pretty regularly, usually removed from old conservatories. Wish I lived over there, I would have bought hundreds by now, as they often go cheap (in quantity)-- I'd use them for a greenhouse roof.
They don't appear to be walkable, unlike the heavier rectangular flat kind (or floor tiles/prisms, the larger, lighter-duty relatives of vault lights).
Don't know when the earlier sort were made, or by whom, but they are still being made now (as googles found out). My flat ones are all well marked, but the older Spanish tile sort are not.
Wish I knew when these first came out, and who was making them-- whose idea it was. It was a good idea-- glass lasts just about forever in the weather, so I can see lots of nice applications for these. Front stoop, anyone? Sun room? Garage would be nice, providing they block all UV.
--ian