The use of manganese as a decolourant as mentioned by Sue - goes back a long way, though I'm also ignorant of whether modern recipes include this method to clear the unwanted discolouration - purple looking shades don't seem to be apparent on modern production stuff - perhaps the sand is washed more thoroughly now
Unsure of the meaning of the word crystal used in this thread - possibly lead crystal (used for most cut glass), though it may be that the Riihimaki pieces mentioned here aren't examples of cut glass, so unlikely to be lead crystal - unfortunately, crystal is used often simply to describe clear/uncoloured glass.
I doubt that any of the colours would fade, but in addition to the other v.g. reasons already mentioned, for not putting glass on a window sill, might be that you're advertising you have collectible glass, and this just might encourage burglary. Perhaps put the collection in a cabinet and illuminate with strip lighting?? Glass that's unprotected and on window sills is a disaster waiting to happen - dusting, pets, partners, children - plus it needs cleaning as they simply become dust traps.