HI , I was going to suggest the same as Frank , though I am unsure as to how long this effect takes to occur on glass I am sure its in the hundreds of years ,though i suppose a lot would depend on the soil conditions, you may well have a fragment of ancient glass and certainly worth the investigation , though I am sure it will never have any monetary value it will always be a fascinating object ,attached are some shots of a Roman piece i have c 150 AD showing the same wonderfull iridescence